Electron Correlations and Two-Photon States in Polycyclic Aromatic Hydrocarbon Molecules: A Peculiar Role of Geometry

We present numerical studies of one- and two-photon excited states ordering in a number of polycyclic aromatic hydrocarbon molecules: coronene, hexa-peri-hexabenzocoronene and circumcoronene, all possessing $D_{6h}$ point group symmetry versus ovalene with $D_{2h}$ symmetry, within the Pariser-Parr-Pople model of interacting $\pi$-electrons. The calculated energies of the two-photon states as well as their relative two-photon absorption cross-sections within the interacting model are qualitatively different from single-particle descriptions. More remarkably, a peculiar role of molecular geometry is found. The consequence of electron correlations is far stronger for ovalene, where the lowest spin-singlet two-photon state is a quantum superposition of pairs of lowest spin triplet states, as in the linear polyenes. The same is not true for $D_{6h}$ group hydrocarbons. Our work indicates significant covalent character, in valence bond language, of the ground state, the lowest spin triplet state and a few of the lowest two-photon states in $D_{2h}$ ovalene but not in those with $D_{6h}$ symmetry.Comment: 11 pages, 3 figures, 3 table

Growth and Characterization of Fe0.95Se0.6Te0.4 Single Crystal

In this paper we present the single crystal growth of Fe0.95Se0.6Te0.4 high TC superconducting sample by the modified Bridgman technique. The x-ray diffraction pattern shows the single crystal nature of the sample, as only (00l) peaks are detectable. The stoichiometric composition has been verified by energy dispersive x-ray analysis. The superconducting transition temperature at 14 K was confirmed through DC magnetization (ZFC-FC) and resistivity measurements. By analyzing the isothermal M-H curves, we determined the value of H_c1 (0) ~360 Oe by extrapolating the data. The temperature coefficient of resistivity obtained using the power law fitting was found to be 0.6. The obtained Raman spectra at room temperature can be interpreted with the tetragonal crystal structure and space group P4/nmm.Comment: conference pape

Study of Performance of Security Protocols in Wireless Mesh Network

Wireless Mesh Networks (WMNs) represent a good solution to providing wireless Internet connectivity in a sizable geographic area; this new and promising paradigm allows for network deployment at a much lower cost than with classic WiFi networks. Standards-based wireless access takes advantage of the growing popularity of inexpensive Wi-Fi clients,enabling new service opportunities and applications that improve user productivity and responsiveness. The deployment of WMNs, are suffered by : (i) All, the communications being wireless and therefore prone to interference, present severe capacity and delay constraints, (ii) The second reason that slows down the deployment of WMNs is the lack of security guarantees. Wireless mesh networks mostly susceptible to routing protocol threats and route disruption attacks. Most of these threats require packet injection with a specialized knowledge of the routing protocol; the threats to wireless mesh networks and are summarized as (i) External attacks: in which attackers not belonging to the network jam the communication or inject erroneous information, and (ii) Internal attacks: in which attackers are internal, compromised nodes that are difficult to be detected. The MAC layers of WMN are subjected to the attacks like Eavesdropping, Link Layer Jamming Attack, MAC Spoofing Attack, and Replay Attack. The attacks in Network Layer are: Control Plane Attacks, Data Plane Attacks, Rushing attack, Wormhole attack, and Black Hole Attack. In this project work we are concern with the threats related to Network layer of WMN based upon 802.11i and analysis the performance of secure routing protocols and their performance against the intrusion detection

Optimal operating conditions and characteristics of acetone/CaF_2 detector for inverse photoemission spectroscopy

Performance and characteristics of a band-pass photon detector using acetone gas and CaF_2 window (acetone/CaF_2) have been studied and compared with an ethanol/MgF_2 detector. The optimal operating conditions are found to be 4 mbar acetone pressure and 745+/-20 V anode voltage. The count rate obtained by us is about a factor of 3 higher than what has been reported earlier for the acetone detector. Unlike other gas filled detectors, this detector works in the proportional region with very small dead time (4 micro sec). A detector band-pass of 0.48+/-0.01 eV FWHM is obtained.Comment: Review of Scientific Instruments 76, 066102 (2005

Nonlinear dynamics of large amplitude dust acoustic shocks and solitary pulses in dusty plasmas

We present a fully nonlinear theory for dust acoustic (DA) shocks and DA solitary pulses in a strongly coupled dusty plasma, which have been recently observed experimentally by Heinrich et al. [Phys. Rev. Lett. 103, 115002 (2009)], Teng et al. [Phys. Rev. Lett. 103, 245005 (2009)], and Bandyopadhyay et al. [Phys. Rev. Lett. 101, 065006 (2008)]. For this purpose, we use a generalized hydrodynamic model for the strongly coupled dust grains, accounting for arbitrary large amplitude dust number density compressions and potential distributions associated with fully nonlinear nonstationary DA waves. Time-dependent numerical solutions of our nonlinear model compare favorably well with the recent experimental works (mentioned above) that have reported the formation of large amplitude non-stationary DA shocks and DA solitary pulses in low-temperature dusty plasma discharges.Comment: 9 pages, 4 figures. To be published in Physical Review

Theory of nonlinear optical properties of phenyl-substituted polyacetylenes

In this paper we present a theoretical study of the third-order nonlinear optical properties of poly(diphenyl)polyacetylene (PDPA) pertaining to the third-harmonic-generation (THG) process. We study the aforesaid process in PDPA's using both the independent electron Hueckel model, as well as correlated-electron Pariser-Parr-Pople (P-P-P) model. The P-P-P model based calculations were performed using various configuration interaction (CI) methods such as the the multi-reference-singles-doubles CI (MRSDCI), and the quadruples-CI (QCI) methods, and the both longitudinal and the transverse components of third-order susceptibilities were computed. The Hueckel model calculations were performed on oligo-PDPA's containing up to fifty repeat units, while correlated calculations were performed for oligomers containing up to ten unit cells. At all levels of theory, the material exhibits highly anisotropic nonlinear optical response, in keeping with its structural anisotropy. We argue that the aforesaid anisotropy can be divided over two natural energy scales: (a) the low-energy response is predominantly longitudinal and is qualitatively similar to that of polyenes, while (b) the high-energy response is mainly transverse, and is qualitatively similar to that of trans-stilbene.Comment: 13 pages, 7 figures (included), to appear in Physical Review B (April 15, 2004